Hi All,
We have a group meeting with Professor George Schatz from 4-530 at the theory couches. His
abstract is below. I hope to see you all there.
Best,
Thomas
Plasmon-molecule interactions
George C. Schatz
Northwestern University, Evanston IL 60208-3113 USA
This talk describes recent theory developments concerned with the optical
properties of plasmonic materials, with emphasis on understanding plasmon enhanced
spectroscopic techniques such as surface enhanced Raman spectroscopy (SERS),
plasmon-enhanced photochemistry, and the coupling of plasmons to excitons. The
cornerstone of this work is computational electromagnetics, which provides the ability to
solve Maxwell’s equations exactly for a given nanoparticle structure and with assumed
dielectric functions. A number of methods for doing these calculations are available, and
in the first part of the talk I will review how these calculations are done, and I will
demonstrate their use to study the extinction spectra and SERS of silver and gold
nanoparticles and other nanostructures. In addition, I will describe very recent
applications concerned with the optical properties of nanoparticle superlattices that
constitute a type of metamaterial that exhibits unusual optical properties.
The second half of the talk will focus on problems where one needs to couple classical
electrodynamics for metal particles to quantum mechanics (usually TDDFT) for molecules
near the nanoparticles. These theories will be developed both in the frequency and time
domains, and the inclusion of both electromagnetic interactions and chemical interactions
between the metal nanoparticle and molecular adsorbate are considered. We demonstrate the
use of these methods with applications to SERS and to plasmonic solar cells. In addition,
we describe examples of plasmon-exciton interactions, such as occurs in plasmon-enhanced
lasing. Here we show how plasmons can interact with molecules to enhance both spontaneous
and stimulated emission.
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