Marlon G. Cummings
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From: Catherine M Bourgeois <cmbourg(a)mit.edu>
Date: March 4, 2016 at 9:37:27 AM EST
To: efrc-all <efrc-all(a)mit.edu>du>, perovskite-seminars
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Subject: Excitonics/Perovskites Seminar: Eric Hoke, Wed. Mar 9 at 4:30 pm
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CENTER FOR EXCITONICS Seminar Series:
Perovskite Seminar:
Reversible and irreversible ion migration processes in lead halide perovskites for
photovoltaics
March 9, 2016 at 4:30 PM/36-462
Eric Hoke
Standord University, Draper Laboratory
Lead hybrid perovskites are a promising family of photovoltaic absorber materials that
have achieved power conversion efficiencies of over 20%. Lead halide perovskites are ionic
materials with a low lattice energy which are unusual properties for a photovoltaic
material. It has been conjectured that this ionic character may be responsible for the
material’s defect-tolerant optoelectronic properties that have enabled its success as an
efficient photovoltaic material. However, lead halide perovskites are highly susceptible
to ion migratory processes which pose a significant challenge to the commercialization of
stable devices.
In this talk, I will present experimental evidence for a variety of ionic migration
processes in perovskite thin films resulting from optical or electrical excitation. We
observe from in-situ XRD measurements that bromine-rich (0.2<x<1) CH3NH3Pb(BrxI1-x)3
and other mixed-halide perovskites undergo a structural transformation under
photoexcitation, segregating into two distinct perovskite phases over the course of
minutes. The optical properties are also changed by this transformation resulting in the
appearance of intense photoluminescence and absorption features from a lower bandgap
phase. The perovskite surprisingly reverts back to its original structure and starting
optical spectra when left in the dark. We suggest that photoexcitation induces halide
segregation, resulting in iodide-rich domains. These lower bandgap domains act as traps
and are likely responsible for the poor open circuit voltages generated by large bandgap,
bromine-rich (0.2<x<1) CH3NH3Pb(BrxI1-x)3 solar cells.
Perovskite solar cells frequently exhibit hysteretic behavior, which is greatly
aggravated by the presence of moisture. The influence of electric field and moisture on
perovskite films was investigated using a combination of photocurrent, optical, Raman, and
Auger mapping techniques on lateral thin-film devices. These studies suggest that
irreversible field-induced degradation in air occurs via a hydrated phase, in which the
organic cation is loosely bound and can drift in response to an electric field, finally
degrading the material to PbI2.
Eric Hoke was recently the Associate Director of the Center of Advanced Molecular
Photovoltaics at Stanford University. He completed his PhD from Stanford University in
2012 as a Fannie & John Hertz fellow and National Science Foundation Graduate Research
fellow where he studied light harvesting mechanisms and degradation processes in organic
photovoltaics and dye sensitized solar cells. Dr. Hoke recently joined Draper Laboratory
as a member of Senior Technical Staff where he is developing imaging systems.
This talk is part of the Perovskites Seminar Series organized by Sam Stranks and
sponsored by the Center for Excitonics. For more info contact Sam: stranks(a)mit.edu
Light refreshments will be served
The Center For Excitonics Is An Energy Frontier Research Center Funded By The U.S.
Department Of Energy,
Office Of Science And Office Of Basic Energy Sciences