Center for Excitonics Seminar Series Announcement The Center for Excitonics is an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science and Office of Basic Energy Sciences The Center for Excitonics invites you to join us at the next seminar of the Spring 2010 series. Please forward this information on to others who might be interested in attending this and other center seminars. Title: Hot Electron Transfer from Semiconductor Nanocrystals Presenter: William Tisdale Organization: Department of Chemical Engineering and Materials Science University of Minnesota Date: March 30, 2010 Time: 3:00 - 4:00pm Place: Haus Room 36-428 Center URL: www.rle.mit.edu/excitonics Seminar URL: www.rle.mit.edu/excitonics/tisdale-033010.html Abstract In conventional semiconductor solar cells, absorption of photons with energies greater than the semiconductor band gap generate “hot” charge carriers that quickly “cool” before all of their energy can be captured – a process that limits device efficiency. Semiconductor nanocrystals (or quantum dots) have been touted as promising materials for photovoltaics because discretization of their electronic energy levels can slow down this cooling process, which might enable the extraction of photogenerated charge carriers before their excess energy is converted to heat. In this talk, I will demonstrate sub-50 fs electron transfer from hot energy levels of PbSe nanocrystals to delocalized conduction band sates of TiO2. In order to make these measurements, we developed the use of optical second harmonic generation for femtosecond time-resolved studies of interfacial charge separation. I will discuss the information we obtain from this technique as well as the effect of temperature, nanocrystal size, and surface chemistry. Additionally, I will show how ultrafast electron transfer excites coherent vibration of the first layer of TiO2 surface atoms, whose collective atomic motions can be followed in real time. Bio Will received his bachelor’s degree in Chemical Engineering (magna cum laude) from the University of Delaware in 2005 and is currently pursuing a Ph.D. in Chemical Engineering at the University of Minnesota under the direction of Professors David Norris, Eray Aydil, and Xiaoyang Zhu (now at the University of Texas – Austin). He is the recipient of an NSF IGERT Fellowship and a University of Minnesota Doctoral Dissertation Fellowship. His research interests lie in the understanding of excited state dynamics near surfaces and interfaces and the application of this understanding toward development of novel photovoltaic technologies.