---------- Forwarded message ----------
From: MRS Materials Research Society <enews(a)mrs.org>
Date: Tue, Nov 29, 2011 at 5:31 PM
Subject: 2011 Materials Research Society Fall Meeting Scene - Days One and
Two
To: saikinsk(a)gmail.com
**
<http://track.mrs.org/y/?e=31215%21%21t%21%21480%21%210%21%2136612%21%21saikinsk@gmail.com%21%21331%21%210%21%210%21%210%21%21http%3A%2F%2Fwww%2Emrs%2Eorg%2Ffall2010>
<http://track.mrs.org/y/?e=31216%21%21t%21%21480%21%210%21%2136612%21%21saikinsk@gmail.com%21%21331%21%210%21%210%21%210%21%21http%3A%2F%2Fwww%2Emrs%2Eorg%2Ffall2010>
<http://track.mrs.org/y/?e=31217%21%21t%21%21480%21%210%21%2136612%21%21saikinsk@gmail.com%21%21331%21%210%21%210%21%210%21%21%20http://www.2spi.coml>
*SPI
Supplies*<http://track.mrs.org/y/?e=31218%21%21t%21%21480%21%210%21%2136…
Silicon Nitride Membrane Window Grids
Visit MRS Booth 1202
------------------------------
<http://track.mrs.org/y/?e=31219%21%21t%21%21480%21%210%21%2136612%21%21saikinsk@gmail.com%21%21331%21%210%21%210%21%210%21%21http%3A%2F%2Fwww%2Eharrickplasma%2Ecom%2Fmrs%5Fad>
*Harrick Plasma,
Inc.*<http://track.mrs.org/y/?e=31220%21%21t%21%21480%21%210%21%2136612%…
Surface Cleaning,
Activation, Pre-bond Preparation
------------------------------
<http://track.mrs.org/y/?e=31221%21%21t%21%21480%21%210%21%2136612%21%21saikinsk@gmail.com%21%21331%21%210%21%210%21%210%21%21http%3A%2F%2Fwww%2Epelletron%2Ecom>
*National
Electrostatics
Corp.*<http://track.mrs.org/y/?e=31222%21%21t%21%21480%21%210%21%2136612…
Ion Beams, RBS, PIXE,
AMS, MeV implant
Visit MRS Booth 311
------------------------------
*MMR Technologies*
<http://track.mrs.org/y/?e=31223%21%21t%21%21480%21%210%21%2136612%21%21saikinsk@gmail.com%21%21331%21%210%21%210%21%210%21%21http%3A%2F%2Fwww%2Emmr%2Dtech%2Ecom>Microcryogenic
and
Thermal Stage Systems
Visit MRS Booth 1003
------------------------------
<http://track.mrs.org/y/?e=31224%21%21t%21%21480%21%210%21%2136612%21%21saikinsk@gmail.com%21%21331%21%210%21%210%21%210%21%21http%3A%2F%2Fwww%2Eadvhealthmat%2Ecom>
*Wiley*<http://track.mrs.org/y/?e=31225%21%21t%21%21480%21%210%21%2136612%21%21saikinsk@gmail.com%21%21331%21%210%21%210%21%210%21%21http%3A%2F%2Fwww%2Eadvhealthmat%2Ecom>
New journal:
Advanced Healthcare Materials
Visit MRS Booth 114
------------------------------
<http://track.mrs.org/y/?e=31226%21%21t%21%21480%21%210%21%2136612%21%21saikinsk@gmail.com%21%21331%21%210%21%210%21%210%21%21http%3A%2F%2Fwww%2Egatan%2Ecom>
*Gatan
Inc.<http://track.mrs.org/y/?e=31227%21%21t%21%21480%21%210%21%2136612%2…
*
The Leader in
EM Instrumentation
Visit MRS Booth 600
------------------------------
<http://track.mrs.org/y/?e=31228%21%21t%21%21480%21%210%21%2136612%21%21saikinsk@gmail.com%21%21331%21%210%21%210%21%210%21%21http%3A%2F%2Fwww%2Eglobalfoundries%2Ecom>
*
GLOBALFOUNDRIES*<http://track.mrs.org/y/?e=31229%21%21t%21%21480%21%210%…
The first truly
global foundry
------------------------------
<http://track.mrs.org/y/?e=31230%21%21t%21%21480%21%210%21%2136612%21%21saikinsk@gmail.com%21%21331%21%210%21%210%21%210%21%21http%3A%2F%2Fwww%2Eneaspec%2Ecom>
*Neaspec
GmbH*<http://track.mrs.org/y/?e=31231%21%21t%21%21480%21%210%21%2136612%…
Infrared spectroscopy with 10nm spatial-resolution
Visit MRS Booth 1102
------------------------------
<http://track.mrs.org/y/?e=31232%21%21t%21%21480%21%210%21%2136612%21%21saikinsk@gmail.com%21%21331%21%210%21%210%21%210%21%21http%3A%2F%2Fwww%2Ecrcpress%2Ecom%2Fecommerce%5Fproduct%2Fbrowse%5Fbook%5Fcategories%2Ejsf%3Bjsessionid%3D1aOw7ZHyfNWe%2BCR6Zs%2Dr4Q%5F%5F%2E37626dd5%2Dd89a%2D32c1%2Daef8%2D5f166039641c?category%3DMAT>
*CRC Press/
Taylor & Francis
Group*<http://track.mrs.org/y/?e=31233%21%21t%21%21480%21%210%21%2136612…
New Books from
CRC Press
Visit MRS Booth 104
------------------------------
<http://track.mrs.org/y/?e=31234%21%21t%21%21480%21%210%21%2136612%21%21saikinsk@gmail.com%21%21331%21%210%21%210%21%210%21%21http%3A%2F%2Fwww%2Ewhitaker%2Eorg>
*Whitaker International
Program*<http://track.mrs.org/y/?e=31235%21%21t%21%21480%21%210%21%21366…
Biomedical Engineering Grants
Visit MRS Booth 221
------------------------------
<http://track.mrs.org/y/?e=31236%21%21t%21%21480%21%210%21%2136612%21%21saikinsk@gmail.com%21%21331%21%210%21%210%21%210%21%21http%3A%2F%2Fwww%2Emicrospectra%2Ecom%2Fcomponent%2Fcontent%2Farticle%2F37%2Devents%2F346%2Dmrs>
*CRAIC
Technologies*<http://track.mrs.org/y/?e=31237%21%21t%21%21480%21%210%21%…
Spectroscopy of
microscopic sample areas
Visit MRS Booth 1209
------------------------------
<http://track.mrs.org/y/?e=31238%21%21t%21%21480%21%210%21%2136612%21%21saikinsk@gmail.com%21%21331%21%210%21%210%21%210%21%21http%3A%2F%2Fwww%2Eattolight%2Ecom%2F>
*Attolight
AG*<http://track.mrs.org/y/?e=31239%21%21t%21%21480%21%210%21%2136612%21…
Discover the new easy Cathodoluminescence
Visit MRS Booth 821
------------------------------
<http://track.mrs.org/y/?e=31240%21%21t%21%21480%21%210%21%2136612%21%21saikinsk@gmail.com%21%21331%21%210%21%210%21%210%21%21http%3A%2F%2Fsales%2Ehamamatsu%2Ecom%2Finfo%2Fquantaurus%2Findex%2Ephp?src%3DUS%2Dmrs111129qntn%20>
*Hamamatsu
Corporation*<http://track.mrs.org/y/?e=31241%21%21t%21%21480%21%210%21%2…
Absolute Quantum Yield Measurement System
Visit Booth 524
------------------------------
<http://track.mrs.org/y/?e=31242%21%21t%21%21480%21%210%21%2136612%21%21saikinsk@gmail.com%21%21331%21%210%21%210%21%210%21%21http%3A%2F%2Fwww%2Ekelvinprobe%2Ecom%20>
*KP
Technology*<http://track.mrs.org/y/?e=31243%21%21t%21%21480%21%210%21%21…
Scanning Kelvin
Probe Photovoltage Spectroscopy
Visit MRS Booth 829
------------------------------
<http://track.mrs.org/y/?e=31244%21%21t%21%21480%21%210%21%2136612%21%21saikinsk@gmail.com%21%21331%21%210%21%210%21%210%21%21http%3A%2F%2Fwww%2Ethermoscientific%2Ecom%2Framan>
*Visit MRS Booth
416*<http://track.mrs.org/y/?e=31245%21%21t%21%21480%21%210%21%2136612%2…
*[image: MRS Meeting
Blog]<http://track.mrs.org/y/?e=31246%21%21t%21%21480%21%210%21%2136612%…
Blog<http://track.mrs.org/y/?e=31247%21%21t%21%21480%21%210%21%2136612%2…
<http://track.mrs.org/y/?e=31248%21%21t%21%21480%21%210%21%2136612%21%21saikinsk@gmail.com%21%21331%21%210%21%210%21%210%21%21http%3A%2F%2Fwww%2Efacebook%2Ecom%2Fgroups%2Ephp?ref%3Dsb%23%2Fgroup%2Ephp?gid%3D214830894497>
Facebook<http://track.mrs.org/y/?e=31249%21%21t%21%21480%21%210%21%21366…
<http://track.mrs.org/y/?e=31250%21%21t%21%21480%21%210%21%2136612%21%21saikinsk@gmail.com%21%21331%21%210%21%210%21%210%21%21http%3A%2F%2Ftwitter%2Ecom%2FMaterials%5FMRS>
Twitter<http://track.mrs.org/y/?e=31251%21%21t%21%21480%21%210%21%213661…
*
*Meeting Scene Days 1 and 2, Sunday and Monday*
Look around you. If Thanksgiving is just past and you find yourself in
Boston surrounded by more than 5,000 materials scientists, then you must be
attending the 2011 MRS Fall Meeting & Exhibit! This version of our
longstanding Fall Meeting kicked off on what we called "Super Sunday" with
seven tutorials, the Acta Materialia Materials and Society Award Forum,
four professional development workshops including one on Careers in
Academia, and the Fred Kavli Distinguished Lectureship in Nanoscience by
Mark E. Davis of Caltech.
The full technical program started on Monday, with accomplished invited
speakers giving perspectives on their particular slice of the materials
science field, while somewhere a graduate student was presenting a talk to
her peers for the first time. Symposium X got off to a great start with a
panel of government experts giving an overview of the Materials Genome
Initiative, which will start funding projects in FY 2012. At the Plenary
Session in the evening, MRS President Jim DeYoreo and Immediate Past
President Dave Ginley introduced the Meeting Chairs, the Congressional
Fellows, the MRS Bulletin Volume Organizers, and two new MRS University
Chapters. Eric J. Amis of United Technologies Research Center followed with
a Plenary Talk that took a detailed look at three materials and three
challenges they present to the materials science community. The evening was
topped off by the Student Mixer and a Poster Session. Not a bad way to
spend a Monday!
Welcome back to Boston!
*MEETING HIGHLIGHTS*
- *Fred Kavli Distinguished Lectureship in Nanoscience: Mark E.
Davis*<#133f1f7b7ec6a55a_kavli>
- *Careers in Academia Workshop <#133f1f7b7ec6a55a_academia>*
- *Symposium X: The Materials Genome Initiative<#133f1f7b7ec6a55a_symposiumX>
*
- *Plenary Session: Eric J. Amis* <#133f1f7b7ec6a55a_plenary>
- *Technical Program* <#133f1f7b7ec6a55a_technical>
*Other Links of Interest*
- *Itinerary
Planner<http://track.mrs.org/y/?e=31252%21%21t%21%21480%21%210%21%213661…
*
- *2011 MRS Fall Meeting Author
Index<http://track.mrs.org/y/?e=31253%21%21t%21%21480%21%210%21%2136612%…
*
- * Submission of Proceedings
Papers<http://track.mrs.org/y/?e=31254%21%21t%21%21480%21%210%21%2136612…
*
- *Career
Center<http://track.mrs.org/y/?e=31255%21%21t%21%21480%21%210%21%2136612…
*
*CONNECT WITH US AT THE MEETING*
*Take our Meetings of the Future
survey*<http://track.mrs.org/y/?e=31256%21%21t%21%21480%21%210%21%213661…
*This online
survey<http://track.mrs.org/y/?e=31257%21%21t%21%21480%21%210%21%2136612…
help us to learn what you are looking for in a scientific meeting, and
get your ideas on what future meetings should look like. *Please take a few
minutes to let us know what you think.
*MRS Meetings
Blog*<http://track.mrs.org/y/?e=31258%21%21t%21%21480%21%210%21%2136612%…
*[image: MRS Meeting
Blog]<http://track.mrs.org/y/?e=31259%21%21t%21%21480%21%210%21%2136612%…
*
*The MRS Meeting Experience*
View the MRS Fall Meeting through the eyes of our student bloggers and
reporters. A glimpse of the Meeting as you have never seen it before!
*2011 MRS Fall Meeting Facebook
Group<http://track.mrs.org/y/?e=31260%21%21t%21%21480%21%210%21%2136612%…
*
*<http://track.mrs.org/y/?e=31261%21%21t%21%21480%21%210%21%2136612%21%21saikinsk@gmail.com%21%21331%21%210%21%210%21%210%21%21http%3A%2F%2Fwww%2Efacebook%2Ecom%2Fgroups%2Ephp?ref%3Dsb%23%2Fgroup%2Ephp?gid%3D214830894497>
*
Connect with your fellow 2011 MRS Fall Meeting attendees in the Fall
Meeting Facebook
Group<http://track.mrs.org/y/?e=31262%21%21t%21%21480%21%210%21%2136612%…97>.
Discuss talks and events, get the scoop on local dining and entertainment
options, post pictures, and more.
*Twitter<http://track.mrs.org/y/?e=31263%21%21t%21%21480%21%210%21%2136612%21%21saikinsk@gmail.com%21%21331%21%210%21%210%21%210%21%21http%3A%2F%2Ftwitter%2Ecom%2FMaterials%5FMRS>
*
*<http://track.mrs.org/y/?e=31264%21%21t%21%21480%21%210%21%2136612%21%21saikinsk@gmail.com%21%21331%21%210%21%210%21%210%21%21http%3A%2F%2Ftwitter%2Ecom%2FMaterials%5FMRS>
*
Join in the conversation!
Alan Taub (center), Vice President of General Motors Global Research
and Development, receiving the 2011 Acta Materialia
Materials and Society Award on Sunday.
------------------------------
*** Fred Kavli Distinguished Lectureship in Nanoscience*
*Mark E. Davis, California Institute of Technology
Fighting Cancer with Nanoparticle Medicines—The Nanoscale Matters!*
*The Kavli Foundation supports scientific research, honors scientific
achievement, and promotes public understanding of scientists and their
work. Its particular focuses are astrophysics, nanoscience, and
neuroscience. For more information about the Foundation, visit their
website at
www.kavlifoundation.org.*
Mark E. Davis wants to improve the quality of cancer patients’ lives while
killing the tumors that are trying to kill them. While chemotherapy
treatment has been around since 1955, its necessary introduction into the
bloodstream allows it to systemically attack healthy as well as cancerous
cells in the body, leading to the terrible side effects that decrease the
quality of life: nausea, hair loss, and a compromised immune system, to
name just a few. His alternative approach is to “move the therapy inside
the cancer cell, and then release it.”
Davis’s weapon of choice is organic nanoparticles containing the cancer
killing drug. To be sure, others have tried and are trying this approach,
but Davis is perhaps unique in the attention to metrics he brings to the
investigation. Not content with using any nanoparticles that fit the
standard definition of 1-100 nm dimensions, Davis has tried to pinpoint
precisely the size of the nanoparticle that will most effectively deliver
the drug over an extended period and then leave the body. This has led to
investigations of the holes in “leaky” blood vessels that grow to feed
solid tumors, and the pore sizes of organs like the kidneys, through which
therapeutic nanoparticles must ultimately fit if they are to leave the
body, preventing undesirable build-up. As the title of his talk emphasized,
“the nanoscale matters!”
In his Kavli Lecture, Davis explained the biology to the assembled
materials scientists. Most molecular-based chemotherapy drugs, which are
about 100 times smaller than nanoparticles, exit the body rapidly through
the kidneys as urine, so a high dose has to be administered to ensure that
enough actually reaches the tumor. Once a solid tumor reaches a size of
about 1mm in diameter, the tumor needs new blood vessels to continue
growing. These new blood vessels typically grow quickly but inefficiently,
leaving them “leaky” with holes. These holes can provide a way to get
cancer-killing drugs inside the tumor. But if you are using nanoparticles
as the delivery agent, they must be the right size.
From his decades of study, Davis has determined the 50
nm is the “right
size to do the right thing, in the right place, at the right time.”
That
is, a 50-nm particle can get through the holes in the leaky blood vessels
to deliver the drugs to the tumor without hurting healthy cells along the
way. A 100-nm particle would be too big to pass through the holes and would
get stuck in the blood vessel, while a 10-nm particle would pass through
the pores of the kidneys and never get to the tumor. Through his careful
investigation of particle sizes between 10 and 100 nm, Davis determined
that 50 nm is the generally the correct size for the drug delivery stage.
He emphasized that eventually you want to rid the body of excess
nanoparticles that are no longer delivering drugs, so it is important to
have a mechanism whereby the particles disassemble and pass through the
kidneys.
Starting in 1996, he and his colleagues began working with PEGylated gold
nanoparticles as drug delivery agents to solid tumors. Besides just size,
they experimented with the zeta potential to determine the optimal charge
of the particles. Eventually they settled on a cyclodextrin (a ring of
sugar) along with gold nanoparticles as parts of a linear polymer backbone
to deliver drugs to tumors. Ten years later, in 2006, he was first able to
test this therapy on a human patient with advanced metastatic pancreatic
cancer. The drug was able to circulate and release drugs in the patient for
two days—a long time—without causing side effects. The original patient
survived for another two years and maintained a high quality of life. Now
this CRLX101 therapy is in randomized Phase II trials in patients.
More recently, Davis has been using RNA as a therapeutic agent to attack
cancer. In the RNA interference (RNAi) technique, two pieces of RNA act
together to cut messenger RNA in the cancer cell at a specific spot along
its chain. This prevents the messenger RNA from creating a protein that
would allow the cancer to grow. Davis uses a bathtub analogy to explain the
difference between traditional chemotherapy and RNAi. In chemotherapy, the
proteins keep being made until the tub fills up and they spill on to the
floor; the chemotherapeutic drugs simply mop up these excess proteins. In
contrast, RNAi turns off the faucet.
“I really feel strongly that we are learning the design rules” for creating
therapies to kill cancer, Davis said. “They are going to be complex, but
they are going to be worth it.”
------------------------------
*** Careers in Academia Workshop *
On Sunday afternoon Cammy Abernathy, Peter Green, Debra Rolison, Paul
Braun, Masashi Kawasaki, and Kathy Wahl gave a tutorial to help Ph.D.
students decide on a career path. The tutorial was designed to help them
make informed career decisions; allow them to successfully compete for
academic positions; and enable them to succeed in academic life. Abernathy
led most of the tutorial, focusing extensively on what an academic career
is really like, and comparing it to careers in industry, government labs,
start-ups, etc. The other panelists frequently added to the discussion and
answered students’ questions.
Abernathy first asked the students to consider the following questions: (1)
How much risk can I tolerate? (2) How much intellectual freedom do I need?
(3) Do I want to be a manager? (4) How entrepreneurial am I? (5) Do I like
teaching? (6) Do I value financial rewards over job security? The answers
to these and other questions could lead the students to choose from a job
in industry, a government lab, a 4 or 5 year college, or a research
university. A Ph.D. in science could also lead to a career in law,
medicine, policy, or science journalism, she added.
With the help of Rolison, a Section Head at the Naval Research Laboratory,
who talked about life in a government lab, Abernathy explored the ins and
outs of each potential path. In industry (the management side) you probably
won’t get to publish, but you’ll be well paid. On the other hand, you may
have to relocate frequently. In industrial R&D you’ll probably write a lot
of internal technical memos, but not publish in journals; patents may be
more important. In a start-up, you have to be highly risk tolerant and a
jack of all trades. This can produce high stress but also high
satisfaction. Life at a teaching college will require you to teach 3 to 4
courses a semester, so you had better like student interaction. At a
research university you can expect a lighter teaching load, but you will
need to find the funding to support 5 or 6 graduate students if you want to
get tenure. Still, “a full professor is the most autonomous creature on
the face of the earth,” Abernathy observed.
------------------------------
*** Symposium X: The Materials Genome Initiative*
(View the complete set of presentation slides
here<http://track.mrs.org/y/?e=31265%21%21t%21%21480%21%210%21%2136612%2…
)
A four-person panel of high ranking officials from the White House,
national laboratories, and funding agencies convened to give an overview of
the Materials Genome Initiative (MGI) announced by President Obama in a
June 2011 speech. The speakers were Cyrus Wadia, Assistant Director, Clean
Energy and Materials R&D, White House Office of Science and Technology
Policy; Harriet Kung, Director, Basic Energy Sciences, Department of Energy
(DOE); Ian Robertson, Director, Division of Materials Research, National
Science Foundation (NSF); and Linda Horton, Director of Materials Science
and Engineering, Basic Energy Sciences, DOE.
Wadia started the conversation by saying that the initiative’s motto is
“two times faster and two times cheaper.” That is, the government wants to
enable researchers to develop and bring new materials to market in half the
time and at half the cost compared to past efforts, which typically took 20
to 30 years from lab bench to market. To do this, they are establishing a
“Materials Innovation Infrastructure” that includes the areas of
computational tools, experimental tools, and digital data. Wadia emphasized
that the government is specifically interested in the center of balance at
the intersection of these three segments. The plan is to bring in the
software community to create open platforms and universal access to
computational tools to enable materials researchers to replace some
experiments with simulations. Also, experimentalists need to develop new
techniques and new figures of merit to bridge the
experimental/computational divide. Regarding digital data Wadia said,“We
believe that data transparency encourages innovation.” There is currently
no repository for large amounts of materials data, so a new “ecosystem”
will be built to encourage data sharing. Extending that theme, Wadia
encouraged researchers to think of themselves as an “ecosystem of
collaborators” rather than as individual principal investigators.
Kung gave a historical overview of the time from discovery to application
in the twentieth century, using Teflon (20 to 30 years) and Li-ion
batteries (approximately 20 years) as examples. All renewable energy
sectors in the United States supply less than 8% of our total energy needs,
she said. How can we expedite development of the new materials needed to
increase this percentage rapidly? “By turning to the scientific community
to help formulate this [MGI] plan,” Kung said. She recounted the
conclusions of the Multi-agency Workshop in 2009 and the Department of
Energy’s Computational Materials Science and Chemistry 2010 Workshop:
Creating an Innovative Ecosystem, as the outcomes of this collaboration
with the community. These workshops noted that the federal government needs
to maintain a long-term stewardship of integrated, sustainable software as
an investment in the materials science community. This will enable “broad
access to and adoption of simulation-based engineering and science,” Kung
said.
Ian Robertson said that the idea behind the MGI was to apply the three
elements of the Materials Innovation Infrastructure (computational tools,
experimental tools, and digital data) simultaneously to all seven steps of
the lab-to-market continuum: (1) discovery, (2) development, (3) property
optimization, (4) systems design and integration, (5) certification, (6)
manufacturing, and (7) deployment. Commenting on the digital data element,
Robertson said tha this was not something that the materials science
community has done well in the past. “How can we create a data repository
that we can actually interrogate?” he asked. He suggested that the
materials community might learn from their colleagues in physics and
astronomy about how to handle large data sets. Robertson closed by
mentioning the multi-agency partnerships that we being established to
support the MGI: DOE and NSF for development of the next generation of
characterization tools; NIST, DOE, and NSF for development of standards;
and the Department of Defense and NSF for recruitment of the next
generation of scientists and engineers.
Finally, Linda Horton answered the overarching question of what is
different about the MGI compared to the current research and development
paradigm. MGI will (1) develop tools that will become a materials community
resource and then an industry resource; (2) ensure that theorists and
experimentalists will work together to guarantee scientific robustness; (3)
provide a U.S. computational software suite for materials discovery; and
(4) restore the U.S. to leadership in the materials research field. She
noted that DOE’s Basic Energy Sciences has a budget request for $40 million
for FY 2012, which of course requires congressional approval. Other MGI
funds will be available through other agencies.
------------------------------
*** Plenary Session*
*Eric J. Amis
Director of Physical Sciences, United Technologies Research Center
Three Materials, Three Challenges*
“Materials scientists are not the center of the universe—we’re
enablers,” Eric Amis said at the start of his Plenary Lecture. Amis, the
Director of Physical Sciences at United Technologies Research Center, took
the opportunity to speak about three materials and three related challenges
of some importance to his company and to the audience members.
The first material he discussed was the flexible polymer belt, which the
Otis Elevator Company, owned by United Technologies, used to replace steel
cables in elevators about ten years ago. The 30 mm wide by 3 mm thick
polyurethane-coated steel belt is more flexible, more durable, and quieter
than stainless steel cables. This innovation made it possible to do away
with whole floors at the tops of buildings being devoted to elevator
machinery. The challenge in this case was performance: the flexible polymer
belt could be made thinner and lighter than the cable used previously. “For
some of the tallest buildings in the world, the weight of the rope is the
limiting factor,” Amis said. He went on to discuss a more fanciful idea of
a space elevator with a cable 5,000 km long.
Material number two in his talk was polymeric membranes. Amis reported that
the global market for membrane separation technologies is projected to
reach $16 billion by 2017. He cited examples of membranes being used for
aircraft fuel tank inerting to reduce the amount of oxygen above the fuel
in a tank. By forcing compressed air into a separation device and allowing
the oxygen to permeate out through a membrane, a nitrogen rich blanket is
produced to cover the fuel in the tank. A membrane is also used to remove
dissolved oxygen from jet fuel to improve the fuel’s heat sinking
capability. Amis noted that hollow fiber membranes are used as exchangers
for heat and moisture (dehumidification). He was particularly excited to
talk about flow batteries, which use ion exchange membranes that allow
water and protons through but hold vanadium—an element in the redox
reaction—back. The challenge with membranes is cost, Amis said.
The final materials class was composites, specifically polymer matrix
composites. In bridges, glass fiber reinforced polymer rebar is being used
to replaced steel rebar, reducing corrosion and weight while adding
strength. Engineers have begun wrapping Kevlar mats around this rebar for
seismic strengthening in earthquake prone areas. Transport vehicles such as
automobiles, boats, and airplanes are using an increasing amount of
composites. Much of the new Boeing 787 is built of carbon reinforced
plastic using thermoset materials, Amis said. Wind turbine blades which had
diameters of 15 meters in 1985 now span 126 meters in diameter, with 160
meters coming soon. Composites are used in this application for their light
weight, strength, and stiffness. The challenge in composites is speed,
according to Amis.
United Technologies is working on all three materials and challenges and
many more across the wide range of companies under their corporate
umbrella.
2011 MRS Fall Meeting chairs recognized for their hard work before the
Plenary Session.
(L-R) Paul Braun, Masashi Kawasaki, Kathryn Wahl, and Cammy Abernathy.
------------------------------
***TECHNICAL PROGRAM*
*Symposium A: Material challenges in current and future nuclear technologies
**A1.4 Effect of Cr segregation to UO2 grain boundaries
Minki Hong, University of Florida*
Large grain size decreases the internal pressure of UO2 in nuclear
reactors, so bigger grains are desirable. Cr2O3 is known to be a grain
growth promoter in this system. Minki Hong reported on work that he and his
colleagues at the Computational Materials Science Focus Group at the
University of Florida have done using atomistic simulations to determine
the effects of Cr on grain growth. Their simulations showed that Cr
substitutes for U and tends to segregate at the core of the grain boundary.
Simultaneously, Cr bonds covalently with O in UO2, reducing the ionic
bonding nature of the oxide and enhancing cation diffusivity. This effect
is particular noticeable at grain boundaries. The researchers found that as
the number of Cr atoms at the grain boundary increased, the grain boundary
energy decreased. This led to the conclusion that while Cr promotes grain
growth in UO2, too much Cr could limit grain growth. The optimal amount of
Cr for maximum grain growth is still to be determined.
*Symposium B: Advanced Materials for Fuel Cells
Invited speaker: James E. McGrath, Virginia Tech
B1.1 Disulfonated poly(arylene ether) copolymers as proton exchange
membranes for H2/Air and DMFC fuel cells
*
In an invited talk, James McGrath said that a practical proton exchange
membrane (PEM) should have high proton conductivity at ambient humidity,
good mechanical properties in wet and dry conditions, low fuel and oxidant
permeability, and oxidative and hydrolytic stability. The major
technological challenge is to increase the operating temperature from the
current value of 80°C to the 100-120°C range, while decreasing the relative
humidity (RH) operating range from the current value of 80-100%. Toward
this end, he and his colleagues at Virginia Tech are investigating
sulfonated dichloro diphenylsulfone monomers (SDCDPS) as elements in block
copolymers for use as PEMs.
By carefully creating a nanophase-separated morphology with a sharp
interface between the hydrophilic and hydrophobic blocks of the copolymer,
they were able to increase the water self-diffusion coefficient and obtain
better performance of the PEM at lower relative humidity. In one
experiment, the block copolymer performed comparably to the standard Nafion
PEM at 100°C and 40% RH; it far exceeded the performance of a random
polymer PEM. Interestingly, the researchers found three types of water in
these systems, depending on the morphology of the copolymer: (1)
non-freezable, tightly bound water; (2) freezable, loosely bound water,
with a broad melting behavior; and (3) free water, with the normal sharp
freezing point at 0°C. By annealing the material above the Tg of the
hydrophobic phase, the copolymer morphology self-assembled more quickly,
and the material showed more ductility as RH increased.
Hands-on science demonstration
*Symposium F: Mobile Energy*
*Invited Speaker*: *Rodrigo F. Martins, FCTUNL, Caparica, Portugal*
*F1.1: **Solid state paper battery
*
Cellulose, a major biopolymer available on our planet, is cheap, flexible,
lightweight, recyclable, and has good dielectric properties. In both its
natural and artificial states, cellulose clearly has properties that make
it attractive for use in self-sustained paper-based disposable electronics.
This group has already demonstrated a host of applications like paper-based
transistors, memory, and electrochromic devices. Developing a paper-based
battery to power these devices was clearly a natural extension to their
work. The solid state paper battery comprises a paper electrolyte
sandwiched between thin film electrodes. Parameters like ion content,
porosity, fiber size, hydrophobicity, and hydrophylicity of the paper can
be controlled to attain the desired electrochemical behavior. In addition
to the ions implanted during paper making, the adsorbed water and hydroxyl
ions also help battery operation. The initial paper battery prototypes
using an Al anode and Cu cathode produced 3.4 V and could survive up to 150oC
without degradation in performance. It was also seen that humidity levels
play a key role: short circuit currents scale directly with increase in
humidity. Electrochemical tests reveal that these paper batteries discharge
abruptly, but can be recharged to recover up to 80% of their initial
voltage on exposure to 70% humidity. In the future, these paper batteries
could be used in the cosmetics industry and in medical drug delivery to
inject drugs directly into the skin. A plethora of applications is
envisaged in other areas like RF tags, intelligent packaging, disposable
toys, and origami electronics.
Tim Miller of Spoken Science gives tips
on Mastering Science Presentations with
a little help from Al Gore (background)
*Pritesh Hirala, University of Cambridge, United Kingdom
F1.5: Stretchable electrochemical capacitors: Power for stretchable
electronics
* *
*Pritesh Hiralal started his presentation by stating the meaning of
stretchable electronics from an application viewpoint: As electronic
materials and/or components form across a substrate in a way that allows
the overall substrate to repeatedly deform >> 5% without electrical
failure, the materials should not exceed their elastic limit (for repeated
stretchability). The main target of this research is the creation of
stretchable devices which embed actively in electronics, especially in
elastic structures (e.g., sensors, actuators, etc.). The researchers are
also looking at ordered nanoscale internal structures for controlling the
elasticity. Hiralal discussed an architecture that starts with an
elastomeric substrate, followed by a rigid island platform which has DLC,
polyimide, and active devices such as thin film transistors. These
components are formed by low temperature processes. Finally, stretchable
interconnects made of Au thin films that can be stretched in one or two
dimensions are added.
*
*Jan Yager leads Effective Time Management
Workshop on Sunday*
*
*
Invited Speaker: Manish Chhowalla, Rutgers University
F1.6: Low voltage and flexible electronics based on graphene*
The mantra for this invited talk was that “reduced Graphene Oxide (rGO) is
a flexible material for flexible electronics.” This group has already
demonstrated their ability to tune graphene oxide chemistry by chemical
synthesis routes. In this regard, removing oxygen groups is critical,
particularly to improve electrical conductivity. By pioneering new routes
for O2 removal, a variety of applications was made possible. Among them
were Light Emitting Electrochemical cells (LEC) which use GO as solution
processed electrodes on flexible substrates. These GO layers were also
demonstrated as Hole Transport Layers (HTL) to replace the corrosive
PEDOT:PSS-based HTL. Another use was to replace the platinum-based counter
electrode used in Dye Sensitized Solar Cells (DSSC) by an electrode
comprised of rGO-metal hybrid nanoparticles. Finally, solution processed GO
was used to demonstrate CO2 reduction and low voltage Thin Film Transistors
(TFT) using Self Assembled Monolayers (SAMs).
Monday night's Student Mixer
*Symposium J: Photonic and plasmonic materials for enhanced photovoltaic
performance*
*Invited Speaker: Harry Atwater, Caltech*
*J1.1**: **A thermodynamic approach to artificial photonic materials for
solar energy conversion
*
Dr. Atwater’s talk on a topic at the forefront of current solar energy
research surprisingly began with the thermodynamics of photonics. What he
called this “rather old work” laid the foundation of limiting theories
(like the 1961 Shockley-Queisser efficiency limit), which to this day haunt
those working on increasing the power conversion efficiency of solar cells.
These efficiency limits can be traced to a variety of sources of entropy
gain that occur during the light absorption and energy conversion process.
The main takeaway from this talk was ways to design an optimum solar cell
that minimizes these losses.Three factors are of importance, namely high
internal quantum efficiency, control of radiative emission angles, and
density of states. Novel light collimation techniques like close-packed
arrays of microphotonic collimators can significantly reduce emission
angles, thereby reducing phonon entropy. The traditional 4*n*2 light
trapping limit will no longer suffice as solar cells get thinner and
efficiency values need to climb higher. Here the Atwater group showed that
by generating structures that manipulate the density of states in photonic
materials, they could achieve light trapping levels that exceed traditional
ray-optics-based approaches. The whispering gallery dielectric nanospheres
for light trapping are an example that showed significant absorption
enhancements in thin solar cells. Recent demonstration of a record 28%
efficient single junction GaAs solar cell by Alta Devices generated this
concluding remark from Atwater: “I see no reason why working together we
cannot attain 50-70% efficiencies in the next 10 years or so.”
*Symposium AA: Carbon Nanotubes, Graphene, and Related Nanostructures*
*Invited Speaker: Motoo Yumura, AIST-Nanotube Research Center, Japan
AA1.1: Putting single-walled carbon nanotubes to use as industrial
materials- Recent progress in development of single-walled carbon nanotube
mass production and their development into applications in Japan*
Motoo Yumura spoke straight to the point on recent mass production of
single-walled carbon nanotubes (SWCNTs) and expectations in the near future
both in research and industry. The AIST Nanotube Research Center
concentrates on three major areas:
(1) Development of techniques for controlling, separation, and
characterization of SWCNTs. The idea is to use metal semiconductors to
separate SWCNTs. Also, new techniques like gel-column have the potential
for high throughput.
(2) Technology development for dispersion of SWCNTs. This involves the
thermal-conductive super-growth of SWCNT rubber. These composite
resin/rubbers have high thermal conductivity and are good dispersants.
(3) Safety management of nano-materials. The goal is to develop a quick and
simple method for toxicity assessment, like onsite measurement.
The current mass production technique for producing SWCNTs is by direct
injection pyrolytic synthesis (DIPS). Though quite simple, it does not
produce high quality industrial materials, and thus requires post-treatment
such as purification or modification on the part of the users. But by
precisely controlling the reaction conditions in the DIPS method a
synthesis has been successfully developed by Yumura and colleagues. The
result is high strength fiber SWCNTs with a diameter control of 0.1 nm
precision. Kenji Hata at AIST discovered the super-growth (SG) technology
based on a novel growth technique whose basic elements are ethylene and
water. It allows ultra high efficiency synthesis at a rate 1000 times
faster than current technologies, and ultra-high purity of 99.88% .
*Symposium JJ: Nanofunctional materials, nanostructures and nanodevices
for cancer applications*
*Invited Speaker*: *Michael J. Cima, MIT*
*JJ 2.6*: *Implanted diagnostic devices*
A biopsy is a classical technique used to obtain a tissue sample, which can
then be analyzed to diagnose the presence of cancer and how far it has
progressed. As surgical procedures done in operating rooms, biopsies can be
pretty invasive, especially if they need to be done multiple times during a
patient’s illness. The Cima Lab proposes to implant a tiny device inside
the tissue using the same needle used for the biopsy. The device can then
do further analysis as and when needed by the physician, thereby
eliminating the need for more biopsies. In a typical process, a biomarker
is transported into the device, which interacts with the sensing media to
change the MR contrast. The result can finally be read out on an MRI scan.
This idea was initially tested out using cardiac markers on mice, which can
be used to detect the possibility for heart attacks. The MRI signal from
the implanted device was found to correlate with the magnitude of the heart
attack, a result not observed previously. The devices have also recently
been used to measure the degree of hypoxia (oxygen deficiency) in tumor
cells. Hypoxic tumors need higher doses of radiation to completely damage
the DNA of the tumor cells, and this necessitates higher doses of radiation
therapy to get the same result as non-hypoxic tumors. It has therefore
become important for physicians to measure the degree of hypoxia during the
treatment phase. The Cima lab implanted PDMS/siloxane-based sensors into
mice and successfully used them to measure their oxygen response inside a
MRI scanner, thereby demonstrating the viability of their implantable
diagnostic devices.
------------------------------
------------------------------
*ABOUT THE MEETING SCENE*
- This Meeting Scene e-mail was compiled and edited by Tim
Palucka<palucka(a)mrs.org>rg>,
with writing help from Apprentice Science Reporters B. Reeja Jayan and
Rahul Reddy. Photographs are by Kasia Bruniany of MRS.
- You have received this as a subscriber to the Meeting Scene.
- To *Unsubscribe*, please e-mail info@mrs.
<info@mrs.org>org<braughler@mrs.org>.
- Archived Meeting Scene
Issues<http://track.mrs.org/y/?e=31266%21%21t%21%21480%21%210%21%2136612…
available online.
- View all free MRS e-newsletters and alerts
<http://track.mrs.org/y/?e=31267%21%21t%21%21480%21%210%21%2136612%21%21saikinsk@gmail.com%21%21331%21%210%21%210%21%210%21%21http%3A%2F%2Fwww%2Emrs%2Eorg%2Fs%5Fmrs%2Fsec%2Easp?CID%3D3665%26DID%3D163101>and
subscribe.
© Materials Research
Society<http://track.mrs.org/y/?e=31268%21%21t%21%21480%21%210%21%213661…2F>,
2011
--
********************************************
Semion K. Saikin, PhD
Department of Chemistry and Chemical Biology
Harvard University
12 Oxford Street, Cambridge, MA 02138
email: saykin(a)fas.harvard.edu
phone: (619)212-6649
********************************************