CENTER FOR EXCTIONICS presents: Perovskite Tandems: A Path Towards Stable 27% Efficiencies* May 17, 2017 at 12 noon/RLE Haus room: 36-428 Axel Palmstrom Stanford University [http://www.rle.mit.edu/excitonics/wp-content/uploads/2017/05/AlexP1-199x300…] Hybrid lead halide perovskites are promising candidates for low cost, thin film light absorbers; they have a tunable band gap and have demonstrated efficiencies as high as 22.1%. As such, these materials are of interest for wide-bandgap absorbers in tandem photovoltaics. Hybrid lead halide perovskites are soft materials with rough surfaces and are sensitive to temperature and oxidative conditions, making many deposition processes incompatible with this material. Typical perovskite solar cells employ spin-deposited organic selective transport layers and evaporated metal contacts on top of the perovskite absorber. These organic selective transport layers have a few main drawbacks for tandem solar cells: first, the rough perovskite surface requires thick organic layers for complete coverage, resulting in significant optical losses, second, these organic materials are incompatible with the types of sputter processes used to deposit high quality transparent contacts (such as indium-tin oxide) and third, organic materials are typically poor elemental diffusion barriers; such barriers are important for device stability. We applied tin oxide by atomic layer deposition (ALD) as a dual-purpose layer to achieve electron selectivity and sputter protection with high optical transmission in monolithic perovskite/silicon and perovskite/perovskite tandem devices. I look at methods to push perovskite tandem efficiencies to 27% and beyond through targeted short circuit current density, fill factor and open circuit voltage enhancements while maintaining a stable device architecture. I will focus on the perovskite-tin oxide interface on a range of perovskite compositions. Here I investigate the role of organic surface passivation layers and ALD processing conditions on perovskite degradation and interface energetics, which ultimately affects device open circuit voltage, a key figure of merit towards achieving stable 27% efficient devices. Axel Palmstrom is a graduate student at Stanford University in the group of Stacey Bent pursuing his Ph.D. in Chemical Engineering. He graduated with Highest Honors from the University of California, Santa Barbara in 2012 with a B.S. in Chemical Engineering. His work focuses on the study metal oxide thin films grown by atomic layer deposition for applications in thin film photovoltaics, including electron and hole selective layers, barrier layers and surface passivation. *This talk is part of the Perovskites Seminar Series organized by Juan-Pablo Correa-Baena from MIT's PV Lab and sponsored by the Center for Excitonics. For more info contact Juan-Pablo: jpcorrea@mit.edu<mailto:jpcorrea@mit.edu> The Center For Excitonics Is An Energy Frontier Research Center Funded By The U.S. Department Of Energy, Office Of Science And Office Of Basic Energy Sciences Light refreshments will be served.